Chemical Oxygen Demand (COD) measures the amount of oxygen needed to break down pollutants in wastewater. For food/beverage plants, high COD levels mean harmful organic waste (fats, sugars, proteins) could enter rivers or treatment systems. Regular COD testing keeps you compliant with environmental laws, avoids fines, protects ecosystems, and improves treatment efficiency.
Think of COD like a "pollution calorie counter." It estimates all organic matter in wastewater – from fruit peels to dairy runoff – that would deplete oxygen in rivers if released untreated. Unlike BOD (which only tracks biodegradable waste), COD includes all organics, giving faster, more comprehensive pollution data.
Your wastewater likely contains:
Blood, fats, and meat scraps (slaughterhouses)
Milk, cheese whey, cleaning chemicals (dairies)
Fruit/vegetable pulp, sugars, starches (canneries)
Oils, grease, food coloring (processing plants)
These substances spike COD levels, often reaching 2,000–10,000 mg/L – far above municipal sewage (300–800 mg/L).
Parameter | COD | BOD |
---|---|---|
Measures | All oxidizable organics | Biodegradable organics only |
Test Time | 2-3 hours | 5 days |
Accuracy | Less affected by toxins | Can be skewed by pollutants |
Use COD for: Quick daily checks, toxic wastewater, or processes with non-biodegradable waste. Use BOD for: Long-term impact studies on rivers. |
Lab-Based Reflux Method
How it works: Mix wastewater with strong chemicals (potassium dichromate), heat for 2 hours, measure oxygen used.
Best for: Regulatory compliance, high accuracy.
Limitations: Uses toxic mercury/silver, slow.
Rapid COD Test Kits
How it works: Pre-mixed vials change color based on COD levels; read via spectrophotometer.
Best for: Daily in-plant checks, results in 20 mins.
Limitations: Slightly less precise than lab tests.
Online COD Sensors
How it works: Probes in treatment tanks measure UV light absorption (correlates to COD).
Best for: Real-time monitoring in treatment plants.
Limitations: High upfront cost, needs calibration.
For most food plants: Combine rapid kits (daily) + lab tests (monthly/quarterly).
Sampling:
Collect wastewater at peak discharge times (e.g., after cleaning cycles).
Use clean, sealed containers; test within 24 hours.
Testing:
Follow kit/lab instructions exactly – even small errors skew results.
Wear gloves/goggles (chemicals are corrosive!).
Recording:
Log COD values, sampling time, production volume daily.
Track spikes after specific activities (e.g., tank cleaning).
Action Thresholds:
Warning Level (e.g., 1,500 mg/L): Check equipment, review processes.
Critical Level (e.g., 3,000 mg/L): Halt discharge, investigate source.
Sampling from wrong locations (e.g., post-treatment instead of discharge points).
Ignoring pH levels – extreme pH affects COD accuracy. Adjust to pH 7 first.
Not calibrating tools – sensors/kits drift over time. Calibrate weekly!
Forgetting temperature – record it; COD can vary with heat.
Testing inconsistently – sample same time/day for comparable data.
Regulations vary, but common standards:
USA (EPA): < 1,100 mg/L for meat/poultry plants; < 850 mg/L for dairy.
EU: Typically < 1,500 mg/L for direct discharge.
Best Practice: Aim for < 500 mg/L to avoid surcharges from treatment plants.
Always check local regulations! Non-compliance can mean $10,000+ daily fines.
Pre-treatment: Install grease traps, screens, or settling tanks.
Process Changes: Reuse blanching water, minimize product loss.
Biological Treatment: Use anaerobic digesters for high-COD streams (converts waste to biogas).
Partner: Work with municipal plants – pre-treat to their COD limits.
Test COD weekly (or continuously with sensors).
Combine rapid kits + lab methods for balance of speed/accuracy.
Document everything – regulators love proof of due diligence.
Invest in pre-treatment – it cuts long-term costs and fines.